The first card is from the 2005 Prime Patches set and features a dual color piece of Ryan's jersey from the Astros. I've put a few other cards from this set on my blog before and love some of the cool jumbo jersey and patch cards. This card is half an orange and half a darker orange stripe. The material is not right to be a patch card, but still a really nice card.
2005 Prime Patches Nolan Ryan Jersey
The second Nolan Ryan card is from the 2001 Fleer Platinum set. Fleer probably put out fifteen to twenty products in 2001, but the Platinum set was one of the better releases. The base set was solid and the inserts were above par. This card is from the National Patch Time insert set and features a two color patch of Nolan Ryan from the Texas Rangers.
2001 Fleer Platinum National Patch Time Nolan Ryan Patch